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From Pixelmon Wiki

The Psychium Z is a Z-Crystal exclusively for Psychic-Type Pokémon.

Moves this Z-Crystal can upgrade:

  • Any psychic type move that isn't from the Status category becomes Shattered Psyche.

Moves, abilities or items like Embargo, Klutz or Trick can't make a Pokémon drop the Z-Crystal that it's holding.

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